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Octanol/water partition coefficient determination by VALLME

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In most of the applications, microextraction techniques are employed to isolate and/or enrich target analytes from a given sample in order to make easier (more selective and sensitive) their final determination by an appropriate instrumental technique. However, the versatility of these techniques allows their use in the determination of chemical constants. Researchers from the University of Alicante at Spain have developed a vortex assisted liquid-liquid microextraction (VALLME) procedure to determine the octanol-water partition coefficient (K ow ) in a simple way. K ow is an important parameter that can be used for different purposes like the studies of the bioaccumulation rates of toxicants since K ow is similar to the lipid-water partition coefficient or the proper selection of an extractant in a extraction technique since K ow provides information about the polarity of a compound. In brief, the proposed VALLME procedure consist on the addition of 50 µL of 1-octanol to 10 mL...

8 open access articles dedicated to sample preparation--January 21 2014

We list here some recent articles dedicated to sample preparation (or interesting aspects related to it) which are freely available on internet: 1. An update for human blood plasma pretreatment for optimized recovery of low-molecular-mass peptides prior to CE–MS and SPE–CE–MS http://bit.ly/1b8dfl9 2. Challenges and new directions in analytical sample preparation http://bit.ly/Lqq18Y 3. Pressurised hot water extraction in continuous flow mode for thermolabile compounds: extraction of polyphenols in red onions http://bit.ly/1kGVxPA 4. ICP-MS-based characterization of inorganic nanoparticles—sample preparation and off-line fractionation strategies http://bit.ly/1j9ciPi 5. Single-drop microextraction for bioanalysis: present and future http://bit.ly/1aHLVdP 6. Nanomaterials in Analytical Chemistry http://bit.ly/19KPkx7 7. Organic Solvent-Free Cloud Point Extraction-like Methodology Using Aggregation of Graphene Oxide http://bit.ly/19KQ5q4 8. Influence of P...

Some open access articles dedicated to extraction techniques

We list here some recent articles dedicated to extraction techniques which are freely available on internet: 1. Dynamic solid phase microextraction analysis for airbornemethamphetamine: quantitation using isotopically substituted methamphetamine http://rsc.li/1klwykM 2. Novel Sorbents for Solid–Liquid Extraction http://bit.ly/1a8mZMf 3. Detection of methamphetamine in indoor air using dynamic solid phase microextraction: a supplementary method to surface wipe sampling http://rsc.li/1a8fNQj 4. Optimization of solid phase extraction chromatography for the separation of Np from U and Pu using experimental design tools in complex matrices http://rsc.li/1aHg6S7 5. Optimisation of the solvent extraction of bioactive compounds from Lophatherum gracile  Brongn. using response surface methodology and HPLC-PAD coupled with pre-column antioxidant assay http://rsc.li/1dfKNDM 6. Preconcentration and determination of bisphenol A, naphthol and dinitrophenol from envi...

Most cited articles in microextraction techniques

We list here the most cited articles in microextraction techniques. In this case, the literature survey has been developed searching "microextraction" in article titles, abstracts and keywords. 1. Determination of organic compounds in water using dispersive liquid–liquid microextraction.  Link 2. Headspace solid-phase microextraction.  Link 3. Stir bar sorptive extraction (SBSE), a novel extraction technique for aqueous samples: Theory and principles .  Link 4. Solvent Microextraction into a Single Drop.  Link 5. Solid-Phase Microextraction. A Solvent-Free Alternative for Sample Preparation.  Link 6. Liquid−Liquid−Liquid Microextraction for Sample Preparation of Biological Fluids Prior to Capillary Electrophoresis.  Link 7. Applications of solid-phase microextraction in food analysis.  Link 8. Evolution of solid-phase microextraction technology.  Link 9. Dynamics of organic compound extraction from water using ...